2) Bilayer graphene
As the
name bilayer itself indicates that it consists two layers of graphene. This
form of graphene is used in optoelectronic and nanoelectronics applications.
Bilayers shows tuneable band gap and excitonic condensation makes form very
special in above mention applications. There are different types of stacking of
the two layers. AA-stacked bilayer, AB-stacked by layer and twisted bilayer are
the methods to stack. First bilayer was formed in the year 2004 by Mr. Geim.
CVD is the effective technique to produce bilayers in the large scale.
3) Graphene superlattices
Superlattices formed by
stacking graphene layers which provide fascinating structural element and
highly functional atomic scale. This form of graphene is widly used in
nanoelectronics and photonic devices. Phonon (quantum of vibration of
mechanical) thermal transport can be visualized with help of superlattices.
This is the ideal model which makes possible to understand the wave like and
particle like study of phono.
4) Nanoribbons
Graphene
nanoribbons are also known as nano graphite ribbons having width of just 100nm.
Mitsutaka Fujita first introduced the nanoribbons to the world. It is very
difficult to produce nanoribbons precisely. It has the value of Youngs modulus
of over 1 TPa. Its edge structure is the zigzag manner which decides the
electronic states of ribbon.
5) Quantum dots
Graphene
quantum dots (GQds) are nano particles of the graphene. They are less than
100nm in the size having properties like low toxicity, chemical stability as
well as quantum confinement effect. They are used in biological, energy and
environment applications.
1) 6) Graphene oxide
Graphene oxide formed by
using paper making techniques which oxidized the graphite element forms the
single sheets with strong bonds. It has tensile strength of 32 GPa. It enhanced
the photo conducting properties of the polymers. As graphene is the
vacuum-tight material but after converting into the graphene oxide water and
vapour easily gets passed through it.
7) Graphene fibre
Scalable
and controllable CVD method is effective way to produce graphene films precisely
and this form rose in 2011. CVD delivered tuneable morphology as well as the
pore structure by controlling evaporation of solvents with precise surface
tension. Graphene fibres first used in supercapacitors in 2013 in the solid
state. Fibres provide thermal and electrical conductivity in the greater way,
with the highest mechanical strength. It is widely used in the textile
industry, light weight vehicles, micro electronic devices. It has 80GPa tensile
strength.
1) 8) 3D graphene
Graphene
atoms are hexagonally arranged in such way that they form the three-dimensional
honeycomb structure formed 3D graphene. CVD is mostly used methods to produce
3D structure. 3D graphene came into the picture in the year 2013 by stony
Brook. He fabricated 3D porous and free-standingarchitecture of graphene. He
used radical initiated crosslinking method. Mr. Khurram introduced new
technique of the production that is then-state-of-the-art for the 3D graphene
structure in the year 2016. These 3D graphene are used in the energy storage,
filtration, thermal management and biomedical devises.
9) Pillared graphene
Pillared
graphene is one of the hybrid carbon structure. It consists oriented array of
nanocarbon connected at end of the graphene sheets. This concept arose in 2008
in the mind of George Froudakis and he described theoretically in the
university of Crete in Greece. It is not
implemented yet but it has the great future in the electronic industry. Its
poses useful electronic properties. It can be also useful for hydrogen storage
tank material.
10) Aerogel
One of the
interested forms of graphene is Aerogel. It weighs just 0.16 milligrams per cm3.
Aerogel is obtained from the solution of graphene and carbon nanotubes. This
solution first freezes dried and then dehydrate the solution which produced the
Graphene aerogel. This form has the superior elasticity. It can recover 90% of
the compression. Its absorption capacity is also great which can absorb up to
900 times of its own weight. The rate of absorption is 6808 grams per seconds.
It is the lightest material form ever.
1) 11) Nano coil
Nano coils
are discovered in the year of 2015. Production of nano coils is possible because
of the defect in the material having the hexagonal grids which cause it to
spiral along its edge. When we apply voltage to this nano coils, flowing
current around this coil produced the magnetic field. Solenoid made up of these
coils acts as the quantum conductor. Its current distribution varies in between
of core and the exterior walls which produced nonlinear inductance.
12) Crumpled graphene
Crumped
graphene has wrinkles on the material in the nanoscale. This technique of
crumpling on the graphene is introduced by the Brown university in the year of
2016. For getting this form of graphene the shrink films are used on which
graphene oxide layer deposit. The graphene oxide gets converted into the
superhydrophobic crumpled graphene which is used in the battery electrodes.
Application of Graphene:
A. Applications in Energy
industry
1) Solar cell
From many
of the year’s scientist work to develop lighter, flexible and transparent solar
cells. But the Major problem was of finding of such material which has all the
properties and able to carry current. Indium Tin oxide has been used because it
poses all the properties except flexibility. But discovery of graphene changes
the traditional way and in 2017 researchers managed to apply graphene on solar
cells. So, the flexible and transparent solar cells were produced which can be
mount on cars, cloths, cell phones, etc.
1) Batteries
Graphene enhanced the
working of traditional lithium batteries. It provides longer lifespan, higher
capacity as well faster charging time. Graphene batteries are light in weight
and flexible which makes them to use in the wearable electronics.
A. Applications in medicine
1) Graphene in Dialysis
As
graphene plays various roles in all industry. With addition to that is also
able to filter the blood. Researchers showed that it can be used to filter
blood from chemical and drugs as well. Superiority of graphene is 20 times
greater than the traditional methods.
1) 2) Photothermal therapy
Photothermal therapy is
used to eliminate abnormal cells by irradiating special agent which destroy
those cells with the help of heat. Graphene oxide increase the working and the
effectiveness of this therapy. With the help of graphene oxide, we can implement
both chemo therapy and photothermal therapy combinedly. So that it will give
better result of destroying tumours. Doing this therapy, it can not damage the
healthy cells.
A. Applications in
electronics
1) Transistors
Graphene replaces the
silicon in the production of transistors. This increases speed of computers up
to 1000 times. This will lead technology on the next level as it saves the time
and increases the functionality. Graphene will make the world faster. Graphene
provides high carrier mobility and creates very low noise.
2) Waterproof and Wearable
electronics
Major
problem of electronic devices is that they get damaged when they come in
contact of the water. Graphene is the best solution on such problems. Graphene
is strong, transparent and able to conduct electricity. That’s why engineers of
Lowa state university print the circuits of the device with the help of
graphene flake. With waterproof electronics scientist are also working on
wearable electronics. Graphene made flexible batteries printed on a fabric.
This will create electronic environment friendly and smart e-textile which can
store energy. This will send all digital gadgets in to the history.
1) 3) Flexible and touchscreen
Indium tin
oxide (IOT) is used commercially for the screen of smartphones, computer, etc.
Researchers of Rice university developed graphene thin films for smartphone
which beats the IOT. Graphene provides lower resistance and the higher
transparency which increase the performance of digital devices. Chine has
produced flexible smart phones with help of graphene. This graphene screens are
are strong light in weight and transparent. It gives all the requirement of
smartphone working with great satisfaction. Smart phones made up of graphene
weighs 200 grams only. Hence graphene will bring the technology on the next
level in the future.
A. Applications in sports
1) 1) Shoes
Graphene
is not purely used in shoes but it is used in composite form. It is proven that
sole made of graphene have a life of hundreds of years. University of
Manchester and sport Invo-8 brand produced shoes made up of graphene. These
shoes increase the strength and provide flexibility properties increased by
50%. These shoes are more durable than traditional. Graphene shoes are able to
absorb shock and the impact which could damage the bones and joints. It
protects the body part most efficiently.
1) 2) Rackets
Graphene
is upgrades energy distribution equally. Weight of racket gets reduced whereas
the service speed and the stability gets increased. Tennis equipment company
named as HEAD developed the graphene racket series whose name is “GRAPHENE 360
SPEED PRO”. Novak Djokovic used this racket for the first times. Graphene will
give better performance in the sport field also.
Home Assignment Activity By -
SYDA _B_ Batch - 2_Group - 2
51 - Ahire Mrunal Keshav
52 - Mathpati Vaishnavi Vikas
53 - Sonawane Pushkar Mukesh
54 - Jagtap Sanket Rajendra
55 - Chavan Sanskruti Suresh
Guided By :
Prof. N. S. Kulkarni
Prof. S. V. Patil
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